Inside Back Cover: Multinuclear Ag Clusters Sandwiched by Pt Complex Units: Fluxional Behavior and Chiral‐at‐Cluster Photoluminescence (Angew. Chem. Int. Ed. 19/2021)
نویسندگان
چکیده
Multinuclear precious metal sandwich complexes containing an asymmetric center in the cluster were synthesized as described by Shinnosuke Horiuchi, Keisuke Umakoshi, and co-workers Research Article on page 10654. Reversible multipoint coordination core can endow them with a remarkable stability, allowing separation of enantiomers detection chiroptical properties solution.
منابع مشابه
Spotlights on our sister journals: Angew. Chem. Int. Ed. 15/2018.
MAC it happen : Presented is a study of the synergistic structuredirecting effect of metal–amine complexes (MACs) with different chelating polyamine ligands and imidazolium-based ionic liquid (IL) cations. For the first time, a layered selenidostannate with an asymmetric eight-membered ring, an organic-decorated layered selenidostannate, and a 3D selenidostannate with both the MAC and IL cation...
متن کاملPt-Ag clusters and their neutral mononuclear Pt(II) starting complexes: structural and luminescence studies.
The mononuclear complexes [Pt(bzq)(S^S)] [S^S = pyrrolidinedithiocarbamate (pdtc 1), dimethyldithiocarbamate (dmdtc 2)] were prepared by reaction of [Pt(bzq)(NCMe)(2)]ClO(4) with an equimolecular amount of [NH(4)(pdtc)] and [Na(dmdtc)·2H(2)O] respectively in MeOH. Reactions of 1 and 2 with AgClO(4) in 1 : 1 and 2 : 1 molar ratios rendered the heteropolinuclear compounds [{Pt(bzq)(S^S)Ag}(2)](Cl...
متن کاملED intensivists and ED intensive care units.
a Division of Emergency Critical Care, Mount Sinai School of Medicine, New York, NY, USA b Department of Emergency Medicine, Wayne State University School of Medicine, Detroit, MI, USA c Departments of Critical Care Medicine & Emergency Medicine, University of Pittsburgh, Pittsburgh, PA, USA d Department of Surgery/ Department of Emergency Medicine, University of New Mexico Health Science Cente...
متن کاملCrystal engineering of mixed-metal Ru-Ag coordination networks by using the trans-[RuCl2(pyz)4] (pyz = pyrazine) building block.
In the rational development of new strategies for the crystal engineering of coordination networks[1] and of metal-based supramolecular architectures[2] the use of predetermined building blocks has assumed an increasing relevance in recent times. For example, molecular corners containing transition metals with programmed coordination angles, such as cisprotected PdII and PtII square-planar comp...
متن کاملEnhanced ultraviolet photoluminescence from SiO2 ÕGe:SiO2 ÕSiO2 sandwiched structure
SiO2 /Ge:SiO2 /SiO2 sandwiched structure was fabricated for exploring efficient light emission. After annealed in N2 (O2,1%), this structure shows three photoluminescence ~PL! bands at 293, 395, and 780 nm. The intensity of the 395 nm band is largely enhanced in comparison with that from the monolayered Ge:SiO2 film. Spectral analyses suggest that the three PL bands originate from S1→S0 , T((T)...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Angewandte Chemie
سال: 2021
ISSN: ['1521-3773', '1433-7851', '0570-0833']
DOI: https://doi.org/10.1002/anie.202102851